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|Section2= |Section3= |Section7= |Section8= }} Rhenium(IV) oxide or rhenium dioxide is the inorganic compound with the formula ReO2. This gray to black crystalline solid is a laboratory reagent that can be used as a catalyst. It adopts the rutile structure. ==Synthesis and reactions== It forms via comproportionation:〔G. Glemser "Rhenium (IV) Oxide" Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1480.〕 :2 Re2O7 + 3 Re → 7 ReO2 At high temperatures it undergoes disproportionation: : 7 ReO2 → 2 Re2O7 + 3 Re It forms perrhenates with alkaline hydrogen peroxide and oxidizing acids. In molten sodium hydroxide it forms sodium rhenate:〔G. Glemser "Sodium Rhenate (IV)" Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1483.〕 : 2 NaOH + ReO2 → Na2ReO3 + H2O 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Rhenium(IV) oxide」の詳細全文を読む スポンサード リンク
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